Research On the Discharge Mechanism of Lithium-Ion Battery Negative Electrode
DOI:
https://doi.org/10.54097/8vvj1d07Keywords:
Lithium-ion battery, Material of negative electrode, Lithium storage mechanism, Structure evolution, Cyclic stability.Abstract
The advancement of high-efficiency lithium-ion cells constitutes a critical driver in facilitating the transition toward sustainable energy systems, and the research on cathode materials is of great significance as the core components affecting battery capacity, magnification performance and cycle life. Although a variety of cathode material systems have been developed, including carbon-based materials, alloy materials, metal oxide and new multi-functional materials, they generally have problems such as difficult to consider the capacity and stability, insufficient conductivity, fierce volume expansion or complex interface reaction, which severely restrict the actual application performance. Based on the analysis on the mechanism of lithium storage of cathode materials, the structure evolution characteristics and ion migration behavior of different material systems in the charge and discharge process are systematically analyzed, and the differences of their electrochemical performance are compared. The key factors affecting the lithium storage performance are further discussed, aiming to provide theoretical support and technical ideas for the design and optimization of high-performance cathode materials.
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References
[1] G. Zubi, R. Dufo-López, M. Carvalho. The lithium-ion battery: State of the art and future perspectives, Renewable and Sustainable Energy Reviews, 2018, 89, 292–308.
[2] B. Dudić, Global Development and Sustainability of Lithium-Ion Batteries in Electric Vehicles, Advanced Engineering Letters, 2024, 4, 2, 73–81.
[3] B. Diouf and R. Pode, Renewable Energy. Potential of lithium-ion batteries in renewable energy, 76, 2015, 76: 375–380.
[4] C. Daniel, JOM. Materials and processing for lithium-ion batteries, JOM, 2008, 60, 9, 43–48.
[5] Y. Deng, J. Wu, M. Sun. Associations of occupational exposure to micro-LiNiCoMnO2 particles with systemic inflammation and cardiac dysfunction in cathode material production for lithium batteries, Environmental Pollution, 2024, 332, 121790.
[6] M. Khan, S. Yan, M. Ali. Innovative solutions for high-performance silicon anodes in lithium-ion batteries: Overcoming challenges and real-world applications, Nano-Micro Letters, 2024, 16, 1, 73.
[7] C. Zhang, J. Yang, H. Mi. A carob-inspired nanoscale design of yolk-shell Si@void @TiO2-CNF composite as anode material for high-performance lithium-ion batteries, Dalton Transactions, 2019, 48, 20, 6846–6852.
[8] Z. Yu, L. Cui, B. Zhong. Research Progress on the Structural Design and Optimization of Silicon Anodes for Lithium-Ion Batteries: A Mini-Review, Coatings, 2023, 13, 9, 1502.
[9] J. Lu, Z. Chen, F. Pan. High-Performance Anode Materials for Rechargeable Lithium-Ion Batteries, Electrochemical Energy Reviews, 2018, 1, 35–53.
[10] R. He, Research progress of carbon-based anode materials for lithium-ion batteries, Advances in Engineering Technology Research, 2024, 12, 776-787.
[11] C. Popsel, Silicon-based High Performance Anode Materials for Next Generation Li-Ion Batteries, 2018.
[12] M. M. Rahman, I. Sultana, T. Yang. Lithium Germanate (Li2GeO3): A High-Performance Anode Material for Lithium-Ion Batteries, 2016, 55, 52, 16059–16063.
[13] A. Galashev, Computational Modeling of Doped 2D Anode Materials for Lithium-Ion Batteries, Materials, 2023, 16, 2, 704.
[14] M. Winter and R. J. Brodd, Chemical Reviews. What are batteries, fuel cells, and supercapacitors? 2004, 104, 10, 4245–4269.
[15] J. Hassoun and B. Scrosati, Journal of The Electrochemical Society. Review—Advances in anode and electrolyte materials for lithium-ion batteries, 2015, 162, 14, A2582–A2588.
[16] Y. Wang et al., Nanoscale. Recent advances in carbon anode materials for lithium-ion batteries, 2020, 12, 34, 18072–18088.
[17] H. Wu, G. Zheng, N. Liu. Engineering empty space between Si nanoparticles for lithium-ion battery anodes, 2012, 12, 2, 904–909.
[18] M. N. Obrovac and L. Christensen, Electrochemical and Solid-State Letters. Structural changes in silicon anodes during lithium insertion/extraction, 2004, 7, 5, A93–A96.
[19] S. Yao, J. Zhao, Y. Yang. Recent Progress in Design of Silicon-Based Materials for Lithium-Ion Battery Anodes, 2020, 27: 78–116.
[20] H. Wu, J. Chen, H. Hng. Nanostructured metal oxide-based materials as advanced anodes for lithium-ion batteries, 2012, 4, 8, 2526–2542.
[21] Zhang et al., Two-Dimensional Transition Metal Carbides and Nitrides (MXenes): Synthesis, Properties, and Electrochemical Energy Storage Applications. Energy&Enviromental Material, 2020, 3, 1, 29-55.
[22] M. Naguib, M. Kurtoglu, V. Presser. Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2, 2011, 23, 37, 4248–4253.
[23] Y. Yang, C. Yan, and J. Huang. Research Progress of Solid Electrolyte Interphase in Lithium Batteries, 2021, 37, 11, 2010076.
[24] J. Kawaji et al., Microstructure analysis of Si/graphite composite anode during charge-discharge cycle, Electrochimica Acta, 2023, 447, 10, 142115.
[25] L. Zhang, Z. Yu, X. Wang. Recent Progress of Silicon-Based Anode Materials for Lithium-Ion Batteries, 2017, 8, 43–57.
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